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Monday, March 15, 2010

The uses of horses

Horses are trained and ridden for practical working purposes such as in police work or for controlling herd animals on a ranch. They are also used in competitive sports including, but not limited to, dressage, endurance riding, eventing, reining, show jumping, tent pegging, vaulting, polo, horse racing, driving, and rodeo. Some popular forms of competit

ion are grouped together at horse shows, where horses perform in a wide variety of disciplines. Horses (and other equids such as mules and donkeys) are used for non-competitive recreational riding such as fox hunting, trail riding or hacking. There is public access to horse trails in almost every part of the world; many parks, ranches, and public stables offer both guided and independent riding. Horses are also used for therapeutic purposes, both in specialized paraequestrian competition as well as non-competitive riding to improve human health and emotional development.
Horses are also driven in harness racing, at horse shows and in other types of exhibition, historical reenactment or ceremony, often pulling carriages. In some parts of the world, they are still used for practical purposes such as farming.
Horses continue to be used in public service: in traditional ceremonies (parades, funerals), police and volunteer mounted patrols, and for mounted search and rescue.

Thursday, March 11, 2010

Diethyl ether (Ethoxy ethane)

Diethyl ether, also known as ether, is the organic compound with the formula (CH3-CH2)2O. It is a colorless and highly flammable liquid with a low boiling point and a characteristic odor. It is the most common member of a class of chemical compounds known generically as ethers. It is a common solvent and was once used as a general anesthetic. Ether is sparingly soluble in water (6.9 g/100 mL).

Most diethyl ether is produced as a byproduct of the vapor-phase hydration of ethylene to make ethanol. This process uses solid-supported phosphoric acid catalysts and can be adjusted to make more ether if the need arises. Vapor-phase dehydration of ethanol over some alumina catalysts can give diethyl ether yields of up to 95% .
Diethyl ether can be prepared both in laboratories and on an industrial scale by the acid ether synthesis. Ethanol is mixed with a strong acid, typically sulfuric acid, H2SO4. The acid dissociates producing hydrogen ions, H+. A hydrogen ion protonates the electronegative oxygen atom of the ethanol, giving the ethanol molecule a positive charge:
CH3CH2OH + H → CH3CH2OH2 A nucleophilic oxygen atom of unprotonated ethanol displaces a water molecule from the protonated (electrophilic) ethanol molecule, producing water, a hydrogen ion and diethyl ether.
CH3CH2OH2+ + CH3CH2OH → H2O + H+ + CH3CH2OCH2CH3
This reaction must be carried out at temperatures lower than 150 °C in order to ensure that an elimination product (ethylene) is not product of the reaction. At higher temperatures, ethanol will dehydrate to form ethylene. The reaction to make diethyl ether is reversible, so eventually an equilibrium between reactants and products is achieved. Getting a good yield of ether requires that ether be distilled out of the reaction mixture before it reverts to ethanol, taking advantage of Le Chatelier's principle.
Another reaction that can be used for the preparation of ethers is the Williamson ether synthesis, in which an alkoxide (produced by dissolving an alkali metal in the alcohol to be used) performs a nucleophilic substitution upon an alkyl halide.